===== Oct 28 (Wed) 3.4 generalized probability, delta-func normalization =====
** Responsible party: poit0009, Hydra **
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Please try to include the following
* main points understood, and expand them - what is your understanding of what the points were.
* expand these points by including many of the details the class discussed.
* main points which are not clear. - describe what you have understood and what the remain questions surrounding the point(s).
* Other classmates can step in and clarify the points, and expand them.
* How the main points fit with the big picture of QM. Or what is not clear about how today's points fit in in a big picture.
* wonderful tricks which were used in the lecture.\\
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==== Main points discussed ====
* Normalization of non-normalizable wave function: why makes sense?
* generalized probability interpretation.
* momentum-space based wave function, energy-space based wave function, real-space based wave function (what we have been dealing with)
===Normalization of non-normalizable wave function===
First, we start off with the question of why
And what exactly does this mean?
To begin, we know that we can operate on an eigenfunction as follows:
where we have simply multiplied āpā onto each part of the vector.
>In the past, for some operator āQ,ā its eigenvalue and eigenvector, we can express this relation as
>
>and we tried to normalize the eigenvector so that
>
>or more in general, for two eigenvectors and we will have .
For our current case: , we know where the usual "k" has been replaced with
Then can we normalize this wave function by setting |A| properly so that ?
Let's try.
This is, as you may remember, one way to express the delta function (times 2pi), where should be the argument of the delta function.
Since this form of delta function is not very familiar to us, we need to use substitution to bring it to a more familiar form, where the argument should look like (k-k') form. Also delta function mean something only when it goes inside an integral, and that integral should be over //p// originally, but when we do the substitution to //k//, dp has to be converted to dk in a proper way.
Following this plan, we use a substitution so so we find
where the implied integral variable has changed from //p// to //k//.
This suggests that there is no way to accomplish no matter what value we choose for //A//.
If we give up this idea, and normalize to the delta function, then , but at this point, this is an arbitrary decision. We could have chosen so that equally justifiably as .
In any case, for now, we find
so
then applying this
The above expression is the all important equation representing momentum space,
>Let's remember that we expanded wave functions in terms of stationary-state wave functions (linear combination), , where C_n's can be calculated by .
>
>Furthermore, we learned that |C_n|^2 can be INTERPRETED to be the probability that the particle would be observed to be in the state with energy E_n. To make sure this interpretation makes sense, we also checked that
> and
>.
>To prove that this is possible, we start with where is the Hamiltonian.
>
>With the definition of expectation value,
>
>
>
>=
>
>Here
>
>So it is proven that
Instead of 's, can we use 's to do the same (except the summation will be integral)?
Namely, where plays the role of C_n's. It should be calculable by