===== Oct 28 (Wed) 3.4 generalized probability, delta-func normalization ===== ** Responsible party: poit0009, Hydra ** **To go back to the lecture note list, click [[lec_notes]]**\\ **previous lecture note: [[lec_notes_1026]]**\\ **next lecture note: [[lec_notes_1030]]**\\ **Main class wiki page: [[home]]** Please try to include the following * main points understood, and expand them - what is your understanding of what the points were. * expand these points by including many of the details the class discussed. * main points which are not clear. - describe what you have understood and what the remain questions surrounding the point(s). * Other classmates can step in and clarify the points, and expand them. * How the main points fit with the big picture of QM. Or what is not clear about how today's points fit in in a big picture. * wonderful tricks which were used in the lecture.\\ \\ ==== Main points discussed ==== * Normalization of non-normalizable wave function: why < f_{p}|f_{p'}> =\delta (p-p^{'}) makes sense? * generalized probability interpretation. * momentum-space based wave function, energy-space based wave function, real-space based wave function (what we have been dealing with) ===Normalization of non-normalizable wave function=== First, we start off with the question of why < f_{p}|f_{p'}> =\delta (p-p^{'}) And what exactly does this mean? To begin, we know that we can operate on an eigenfunction as follows: \widehat{p}|f_{p}>=p|f_{p}> where we have simply multiplied ā€œpā€ onto each part of the vector. >In the past, for some operator ā€œQ,ā€ its eigenvalue and eigenvector, we can express this relation as \widehat{Q}|q_{n}>=q_{n}|q_{n}> > >and we tried to normalize the eigenvector so that =1 > >or more in general, for two eigenvectors q_{n} and q_{m} we will have =\delta _{m,n}. For our current case: f_{p}, we know f_{p}=Ae^{i\frac{p}{\hbar}x} where the usual "k" has been replaced with \frac{p}{\hbar} Then can we normalize this wave function by setting |A| properly so that \int_{-\infty}^{\infty}f_{p}^{*}\: f_{p^{'}}\; dx = 1? Let's try. 1 = |A|^{2} \int_{-\infty}^{\infty}e^{-i\frac{p}{\hbar}x}\: e^{i\frac{p'}{\hbar}x}\; dx =|A|^{2} \int_{-\infty}^{\infty}e^{-i\frac{p-p^{'}}{\hbar}x}\; dx This is, as you may remember, one way to express the delta function (times 2pi), where \frac{p-p^{'}}{\hbar} should be the argument of the delta function. =|A|^{2} 2\pi \delta \left ( \frac{p-p^{'}}{\hbar} \right ) Since this form of delta function is not very familiar to us, we need to use substitution to bring it to a more familiar form, where the argument should look like (k-k') form. Also delta function mean something only when it goes inside an integral, and that integral should be over //p// originally, but when we do the substitution to //k//, dp has to be converted to dk in a proper way. Following this plan, we use a substitution p=\hbar k so dp=\hbar dk so we find =2\pi\hbar |A|^{2} \delta (k-k^{'}) where the implied integral variable has changed from //p// to //k//. This suggests that there is no way to accomplish \int_{-\infty}^{\infty}f_{p}^{*}\: f_{p^{'}}\; dx = 1 no matter what value we choose for //A//. If we give up this idea, and normalize f_p to the delta function, then A=\frac{1}{2\pi\hbar}, but at this point, this is an arbitrary decision. We could have chosen so that \int_{-\infty}^{\infty}f_{p}^{*}\: f_{p^{'}}\; dx = 10000\delta(k-k') equally justifiably as \int_{-\infty}^{\infty}f_{p}^{*}\: f_{p^{'}}\; dx = \delta(k-k'). In any case, for now, we find A=\frac{1}{\sqrt{2\pi \hbar}} so f_{p}=\frac{1}{\sqrt{2\pi \hbar}}e^{i\frac{p}{\hbar}x} then applying this =\frac{1}{\sqrt{2\pi \hbar}}\int_{-\infty}^{\infty}e^{i\frac{p}{\hbar}x}\; \Psi (x,t) \; dx The above expression is the all important equation representing momentum space, \Phi(p,t) >Let's remember that we expanded wave functions in terms of stationary-state wave functions (linear combination), |\psi>=\sum C_n \psi_n(x), where C_n's can be calculated by C_n=<\psi_n|\psi>. > >Furthermore, we learned that |C_n|^2 can be INTERPRETED to be the probability that the particle would be observed to be in the state with energy E_n. To make sure this interpretation makes sense, we also checked that >\sum C_{n}=1 and >\sum |C_{n}|^{2}E_{n}=_{\Psi}. >To prove that this is possible, we start with \hat{H}\Psi=E\Psi where \hat{H}=\left( -\frac{\hbar^{2}}{2m}dx+V \right ) is the Hamiltonian. > >With the definition of expectation value, =\int \Psi^{*}(x,t) \: \hat{H} \; \Psi(x,t)\; dx > >=\int \sum C_{n}\Psi_{n}^{*}\; \hat{H}\; \sum C_{m}\Psi_{m}\; dx > >= E_{n}\sum C_{n}^{*}C_{m}\int \Psi_{n}^{*}\Psi_{m}\; dx > >Here \Psi_{m}^{*}\Psi_{n}=\delta_{m,n} > >So it is proven that \sum |C_{n}|^{2}E_{n}= Instead of \psi_n's, can we use f_p's to do the same (except the summation will be integral)? Namely, \Psi(x,t)=\int \Phi(p,t)f_p dp where \Phi(p,t) plays the role of C_n's. It should be calculable by \Phi(p,t)=. Furthermore, |Phi(p,t)|^2 should be interpreted as probability (density). For the last part, we need to be able to show that \int |\Phi(p,t)|^2 dp = 1 and \int p |\Phi(p,t)|^2 dp =

. It turns out that if you choose so that \int_{-\infty}^{\infty}f_{p}^{*}\: f_{p^{'}}\; dx = 1 everything works out. (Students are strongly encouraged to show this claim is true. Some of them may appear in the next quiz! (//Yuichi//) ***This section posted in segments, so it's not complete yet*** ------------------------------------------- **To go back to the lecture note list, click [[lec_notes]]**\\ **previous lecture note: [[lec_notes_1026]]**\\ **next lecture note: [[lec_notes_1030]]**\\